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Model Predictions of Methyl Salicylate Skin Exposure Informed by the Variability of Metabolite Urinary Excretion in Controlled Human Exposures

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• Affiliation: Gillings School of Global Public Health, Department of Environmental Sciences and Engineering
• Human exposure assessments of military protective clothing against vapor intrusion commonly use methyl salicylate (MeS), a simulant for sulfur mustard. Currently, in these exposure assessments the amount of MeS absorbed through the skin after penetrating through the clothing is unknown. A model that relates MeS skin absorption to metabolites in biological samples could provide insight into the total skin exposure. A dynamic mass-transfer model was developed to predict MeS skin absorption and excretion in the urine, when employing a controlled human forearm skin exposure. This model can utilize exposure data to determine human specific skin permeability and toxicokinetic factors. By evaluating many controlled exposure experiments, the model will generate averages and distributions of exposure parameters across the population. The model can then be used to estimate skin exposure from the urine concentrations of those exposed to MeS in field exercises. Ultimately, this could improve the evaluation of protective clothing efficacy.
• Occupational safety
• Environmental science
• Environmental health
• https://doi.org/10.17615/2ceh-en78
• Masters Thesis
• In Copyright - Educational Use Permitted
• Nylander-French, Leena
• Morrison, Glenn
• Ormond, Bryan
• Master of Science
• University of North Carolina at Chapel Hill Graduate School

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New thesis shows Lynch syndrome should be seen as a common condition

by Karolinska Institutet

Sophie Walton Bernstedt from the Gastroenterology and Rheumatology Unit at the Department of Medicine, Huddinge (MedH), is defending her thesis "Risk factors for colorectal cancer and the impact on life in Lynch syndrome," on 24 May, 2024. The main supervisor is Ann-Sofie Backman (MedH).

"We have investigated various risk factors associated with the development of colorectal cancer in Lynch syndrome and what it is like for these patients to live with a greatly increased cancer risk," says Walton Bernstedt.

"There is likely still a large number of patients yet to be identified with Lynch syndrome. It is necessary to identify these patients in time in order to prevent and detect early stage cancer by preventive procedures.

"By implementing routines in follow-up services for this group of patients it is possible to create optimal conditions for early detection. These routines include bowel preparation , but also the quality of the procedure, adaptation to genetic risk but also accommodating psychosocial needs among patients.

"Lynch syndrome no longer should be considered a rare condition. By increasing the knowledge of hereditary cancer in the public we hope to increase the efficiency of cancer preventive measures ."

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Ukraine war latest: Armed ship destroyed in Crimea, Kyiv says; controversial US television host launches show in Russia

Ukraine says it hit and destroyed the Russian missile ship Tsiklon in Crimea over the weekend. Meanwhile, analysts say Moscow is seeking to draw out Kyiv's forces - as Putin makes another significant change to his cabinet.

Thursday 23 May 2024 08:15, UK

• Kyiv claims it has destroyed last Russian warship armed with cruise missiles in Crimea
• Tucker Carlson launches new show in Russia
• Putin sacks minister in new sign of shift in war strategy
• European country now pushing to let Ukraine strike deep into Russia with Western weapons
• Russia using 'understaffed and incohesive forces' in bid to draw out Ukrainian troops
• Big picture: What you need to know as war enters new week

Our live coverage will remain paused today, but let's catch you up on where things stand and on any updates overnight.

• Russia said 35 rockets and three drones were fired into Belgorod and overnight, claiming to have destroyed all of them;
• Blasts were heard in Kherson as Russia shelled the city, said its regional governor Roman Mrochko;
• The leader of Russia's Chechnya region, Ramzan Kadyrov, met  Vladimir Putin and offered to send more fighters to the frontline;
• Volodymyr Zelenskyy issued a fresh plea for upgraded defence systems to protect Ukraine's cities against guided bombs, which he described as the "the main instrument" now used by Moscow';
• A Russian airstrike on Ukraine's northeastern city of Kharkiv yesterday destroyed a cafe, damaged a nearby residential building and set a petrol station ablaze, with local officials saying ten people were wounded.

As we've not been providing rolling coverage of the war in Ukraine today, here is a quick update on what's been happening since this morning. 

One of the most significant new stories is the UK accusing China of providing or preparing to provide lethal aid to Russia for use in the war against Ukraine. 

Defence Secretary Grant Shapps told a news conference this morning that US and British defence intelligence had evidence "lethal aid is now, or will be, flowing from China to Russia and into Ukraine".

He called this a "significant development".

We also heard from the Kremlin this morning, which said "in-depth dialogue" was needed to reduce rising tensions between Russia and the West - particularly with regards to nuclear issues. 

Kremlin spokesperson Dmitry Peskov accused the "collective West" of refusing to engage with Russia despite the potential dangers. 

Here are more of the top stories: 

• Russian forces have taken over the village of Klishchiivka in Ukraine's eastern Donetsk region, close to the city of Bakhmut, according to Russian news agencies 
• At least nine people have been injured in a Russian air attack on the Ukrainian city of Kharkiv
• Russia accused Ukraine of using a drone to attack a non-nuclear facility at the Zaporizhzhia nuclear plant, causing no critical damage
• Moscow said it is bolstering its efforts to protect its energy infrastructure from drone attacks
• Six children were handed over to Ukraine by Russia and reunited with their families, after a deal was brokered by Qatar. 

We're pausing our coverage of the Ukraine war for the moment.

Scroll through the blog below to catch up on today's developments.

Vladimir Putin has praised the late president of Iran, Ebrahim Raisi, and said he was a "reliable partner".

Raisi was killed in a helicopter crash near the Azerbaijan border over the weekend along with his foreign minister and seven others.

Speaking on the leader, Mr Putin said he was "a man of his word" who carried out any agreements the pair made.

"He was truly a reliable partner, a man sure of himself, who acted in the national interest," Russian news agencies quoted Mr Putin as telling Vyacheslav Volodin, chairman of Russia's lower house of parliament.

"He was, of course, a man of his word and it was always good to work with him. What I mean is if we came to an agreement on something, you could be sure the agreement was carried out."

The Kremlin leader asked Mr Volodin, who will be attending memorial events in Iran, to pass on "words of our sincere condolences in connection with this tragedy".

Since the start of the war in Ukraine, Russia has strengthened political, trade and military ties with Iran in a deepening relationship that the US and Israel view with concern.

Heavy fighting in the Pokrovsk area in eastern Ukraine has forced Ukrainian troops to engage in "manoeuvres," the Ukrainian military's general staff have said.

Their report said Pokrovsk, northwest of the Russian-held city of Donetsk, remains the front's "hottest" sector.

"In some areas, the situation requires our troops to engage in manoeuvres," the general staff report reads.

Volodymyr Zelenskyy has referred to the region and adjacent areas as "extraordinarily difficult" in his nightly video address.

Volodymyr Zelenskyy has said allies are taking too long when it comes to decisions on military support for Ukraine.

In an interview with Reuters, the Ukrainian leader said every decision which everyone came to was "late by around one year".

"But it is what it is: one big step forward, but before that two steps back. So we need to change the paradigm a little bit," he said.

"When we're quick, they fall behind. And then there's a gap - six, eight months of unpassed (aid) packages, and then two-three months of supplies - and a year goes by. We would like not to lose the advantage."

Mr Zelenskyy also said Ukraine had never used Western weapons on Russian territory.

A senior Russian diplomat has said that the EU plan to channel profits from frozen Russian assets to Ukraine would have "unpredictable" consequences, according to the TASS news agency.

According to TASS, Kirill Logvinov, Russia's acting permanent representative to the EU in Brussels, told Russia journalists: "The only predictable thing is that those in the EU will be obliged sooner or later to return to our country what has been stolen."

For context : In March the European Commission proposed transferring to Ukraine profits generated by Russian central bank assets frozen in Europe.

The plan would see 90% channeled through the European Peace Facility fund to buy weapons for Ukraine. 

The rest would be used for recovery and reconstruction.

Russia's defence ministry has said it has begun a round of drills involving tactical nuclear weapons. 

The exercises were announced by Russian authorities this month in response to remarks by senior Western officials about the possibility of deeper involvement in the war in Ukraine.

It was the first time Russia has publicly announced drills involving tactical nuclear weapons, although its strategic nuclear forces regularly hold exercises.

According to the ministry's statement, the first stage of the new drills include nuclear-capable Kinzhal and Iskander missiles.

The maneuvers are taking place in the southern military district, which consists of Russian regions in the south.

A Moscow court has ordered a Russian journalist who covered the trials of the late Russian opposition politician Alexei Navalny and other dissidents must  remain in custody pending an investigation and trial on charges of extremism.

Antonina Favorskaya was arrested in March. 

She is accused of collecting material, producing and editing videos and publications for Navalny's Foundation for Fighting Corruption, which had been outlawed as extremist by Russian authorities, according to court officials.

Today, Moscow's Basmanny district court ordered that she remain in custody until at least 3 August.

Kira Yarmysh, Navalny's spokeswoman, said earlier that Ms Favorskaya did not publish anything on the foundation's platforms and suggested that Russian authorities have targeted her because she was doing her job as a journalist.

Former Fox News presenter Tucker Carlson has launched his own show in Russia.

The controversial US media personality, who this year became the first Western journalist to interview Vladimir Putin since Russia invaded Ukraine, will host his show on the state-owned Russia 24 (Rossiya 24).

In the first episode, Carlson will discuss the dangers of ticks and Lyme disease.

Who is Carlson?

Carlson, who has been a vocal supporter of Mr Putin in the past, was sacked from Fox News in April last year.

He took up the prime-time weekday evenings spot on Fox News in 2016 with his show Tucker Carlson Tonight, and quickly established himself as a key player in the network and an influential voice in Republican politics.

The presenter often embraced conspiracy theories and far-right issues. He repeatedly questioned the efficacy of COVID vaccines and compared mandates to "Nazi experiments".

While he found success with viewers, his inflammatory comments caused some advertisers to distance themselves from the programme.

After his departure from Fox News he rebooted his show on X last year, calling Elon Musk's site the last big remaining platform to allow free speech.

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‘being maria’ review: ‘last tango in paris’ star maria schneider gets a behind-the-scenes biopic that starts strong but fizzles out.

Anamaria Vartolomei ('Happening') plays the troubled French actress — alongside Matt Dillon as Marlon Brando — in Jessica Palud's film.

By Jordan Mintzer

Jordan Mintzer

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When New Yorker film critic Pauline Kael wrote a long and heated rave of Bernardo Bertolucci ’s Last Tango in Paris after its premiere in 1972, she stated, among other things, that “this is a movie people will be arguing about for as long as there are movies.”

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The reasons for this are well known, and resurfaced over the past decade alongside the many #MeToo scandals that rocked the film world: For the infamous sequence in Last Tango in which Brando’s character, Paul, anally rapes Schneider’s character, Jeanne, using butter as a lubricant, the actress was never forewarned — the scene wasn’t in the original script — nor was she ever asked for consent. Brando and Bertolucci conspired to take her by surprise, and while the sodomy was simulated, the butter was real, and the entire humiliating experience would have a life-changing effect on Schneider.

Being Maria , directed by Jessica Palud ( Revenir ), who adapted the script from a book by Vanessa Schneider — a journalist for Le Monde and Maria’s younger cousin — is built entirely around that pivotal incident, both for better and for worse. Like the actress herself, whose life and career exploded with Last Tango’s success while unraveling at the same time, the movie loses its way after the scandal surrounding Bertolucci’s film fizzles out.

Before then, Palud paints a convincing portrait of a young woman from a troubled background whose connection to the movies was more personal than professional. When we first meet Maria (the excellent Anamaria Vartolomei from Happening ), she’s on a film set admiring the work of her estranged father, the actor Daniel Gélin (Yvan Attal), who abandoned her as a child.

Through the help of Daniel, Maria starts working as an actress, playing small roles in a handful of films. Soon she’s 19-years-old and sitting in a café opposite Bertolucci (Giuseppe Maggio), who’s decided to cast her in Last Tango , studying her like a caged tiger fascinated by its prey. Bertolucci fans beware: The director comes across here as a pompous and careless prima donna.

Brando (played quite convincingly by a heavily made-up Matt Dillon ) is much more charming and paternalistic, initially taking Maria under his wing to show her the ropes of his profession. In one early scene they shoot together, Maris admires how Brando manages to shed real tears on set, to which he responds: “I wasn’t acting.”

This comes back to bite Maria big time when we arrive at the rape scene and the actress is caught completely off-guard. She trusted both Brando and Bertolucci, but the two wanted her reaction to be so real that they deliberately failed to warn her. After the scene is in the can and Schneider storms off to cry in her dressing room, she’s forced to come back and shoot the second part of the sequence. Like a pro, she does it, and nobody apologizes to her. The best Brando can say is: “It’s only a film.”

The problem with the film is that that scene happens about a half hour in, after which we’re left with a downward and rather predictable spiral that fails to maintain our interest. We see Schneider losing it soon after Last Tango becomes a scandalous sensation — it received an X-rating in the U.S. and was legally banned in Italy, where all prints of the film were burned — partying all night long, dating a heroin addict and becoming one herself, nodding off on set and failing to remember her lines.

Vartolomei is a compelling actress and the camera truly loves her, but there’s only so much she can do with a script that doesn’t have much of a second or third act. Had Palud set the entire movie around the Last Tango shoot and its immediate aftermath, the drama would have perhaps been more compact. Instead, we’re left watching Maria dance in lots of nightclubs, go through withdrawal, get hospitalized, fall in love with a young film student (Céleste Brunnquell) doing a thesis on women in movies, and try to kick her habit for good. Plenty of stuff happens, but there’s no real arc to sustain the material.

Palud’s film asks us to contemplate whether art should always truimph over real people, using Maria Schneider’s sad true story as proof that certain things aren’t worth doing to make a “movie breakthrough.”

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