stoichiometry percent yield homework

Chemistry Steps

General Chemistry

Stoichiometry.

This is a comprehensive, end-of-chapter set of practice problems on stoichiometry that covers balancing chemical equations, mole-ratio calculations, limiting reactants, and percent yield concepts. 

The links to the corresponding topics are given below.

• The Mole and Molar Mass
• Molar Calculations
• Percent Composition and Empirical Formula
• Stoichiometry of Chemical Reactions

Limiting Reactant

• Reaction/Percent Yield
• Stoichiometry Practice Problems

Balance the following chemical equations:

a) HCl + O 2 → H 2 O + Cl 2

b) Al(NO 3 ) 3 + NaOH → Al(OH) 3 + NaNO 3

c) H 2 + N 2 → NH 3

d) PCl 5 + H 2 O → H 3 PO 4 + HCl

e) Fe + H 2 SO 4 → Fe 2 (SO 4 ) 3 + H 2

f) CaCl 2 + HNO 3 → Ca(NO 3 ) 2 + HCl

g) KO 2 + H 2 O → KOH + O 2 + H 2 O 2

h) Al + H 2 O → Al 2 O 3 + H 2

i) Fe + Br 2 → FeBr 3

j) Cu + HNO 3 → Cu(NO 3 ) 2 + NO 2 + H 2 O

k) Al(OH) 3 → Al 2 O 3 + H 2 O

l) NH 3 + O 2 → NO + H 2 O

m) Ca(AlO 2 ) 2 + HCl → AlCl 3 + CaCl 2 + H 2 O

n) C 5 H 12 + O 2 → CO 2 + H 2 O

o) P 4 O 10 + H 2 O → H 3 PO 4

p) Na 2 CrO 4 + Pb(NO 3 ) 2 → PbCrO 4 + NaNO 3

q) MgCl 2 + AgNO 3 → AgCl + Mg(NO 3 ) 2

r) KClO 3 → KClO 4 + KCl

s) Ca(OH) 2 + H 3 PO 4 → Ca 3 (PO 4 ) 2 + H 2 O

Consider the balanced equation:

C 5 H 12 + 8 O 2 → 5CO 2 + 6H 2 O

Complete the table showing the appropriate number of moles of reactants and products.

How many grams of CO 2  and H 2 O are produced from the combustion of 220. g of propane (C 3 H 8 )?

C 3 H 8 (g) + 5O 2 (g) → 3CO 2 (g) + 4H 2 O(g)

How many grams of CaCl 2 can be produced from 65.0 g of Ca(OH) 2 according to the following reaction,

Ca(OH) 2 + 2HCl → CaCl 2 + 2H 2 O

How many moles of oxygen are formed when 75.0 g of Cu(NO 3 ) 2 decomposes according to the following reaction?

2Cu(NO 3 ) 2   → 2CuO + 4NO 2  + O 2

How many grams of MnCl 2  can be prepared from 52.1 grams of MnO 2 ?

MnO 2  + 4HCl → MnCl 2  + Cl 2  + 2H 2 O

Determine the mass of oxygen that is formed when an 18.3-g sample of potassium chlorate is decomposed according to the following equation:

2KClO 3 (s) → 2KCl(s) + 3O 2 (g).

How many grams of H 2 O will be formed when 48.0 grams H 2 are mixed with excess hydrogen gas?

2H 2  + O 2 → 2H 2 O

Consider the chlorination reaction of methane (CH4):

CH 4 (g) + 4Cl 2 (g) → CCl 4 (g) + 4HCl(g)

How many moles of CH 4 were used in the reaction if 51.9 g of CCl4 were obtained?

How many grams of Ba(NO 3 ) 2 can be produced by reacting 16.5 g of HNO 3 with an excess of Ba(OH) 2 ?

Ethanol can be obtained by fermentation – a complex chemical process breaking down glucose to ethanol and carbon dioxide.

                                                  C 6 H 12 O 6    →    2C 2 H 5 OH   +    2CO 2                                                       glucose                   ethanol

How many mL of ethanol (d =0.789 g/mL) can be obtained by this process starting with 286 g of glucose?

36.0 g of butane (C 4 H 10 ) was burned in an excess of oxygen and the resulting carbon dioxide (CO 2 ) was collected in a sealed vessel.

2C 4 H 10 + 13O 2 → 8CO 2 + 10H 2 O

How many grams of LiOH will be necessary to consume all the CO 2 from the first reaction?

2LiOH + CO 2 → Li 2 CO 3 + H 2 O

13. Which statement about limiting reactant is correct?

a) The limiting reactant is the one in a smaller quantity.

b) The limiting reactant is the one in greater quantity.

c) The limiting reactant is the one producing less product.

d) The limiting reactant is the one producing more product.

Find the limiting reactant for each initial amount of reactants.

4NH 3 + 5O 2 → 4NO + 6H 2 O

a) 2 mol of NH 3 and 2 mol of O 2

b) 2 mol of NH 3 and 3 mol of O 2

c) 3 mol of NH 3 and 3 mol of O 2

d) 3 mol of NH 3 and 2 mol of O 2

Note:  This is not a multiple-choice question. Each row represents a separate question where you need to determine the limiting reactant.

How many g of hydrogen are left over in producing ammonia when 14.0 g of nitrogen is reacted with 8.0 g of hydrogen?

N 2 (g) + 3 H 2 (g) → 2 NH 3 (g)

How many grams of PCl 3 will be produced if 130.5 g Cl 2 is reacted with 56.4 g P 4 according to the following equation?

6Cl 2 (g) + P 4 (s) → 4PCl 3 (l)

How many grams of sulfur can be obtained if 12.6 g H 2 S is reacted with 14.6 g SO 2 according to the following equation?

2H 2 S(g) + SO 2 (g) → 3S(s) + 2H 2 O(g)

The following equation represents the combustion of octane, C 8 H 18 , a component of gasoline:

2C 8 H 18 (g) + 25O 2 (g) → 16CO 2 (g) + 18H 2 O(g)

Will 356 g of oxygen be enough for the complete combustion of 954 g of octane?

When 140.0 g of AgNO 3 was added to an aqueous solution of NaCl, 86.0 g of AgCl was collected as a white precipitate. Which salt was the limiting reactant in this reaction? How many grams of NaCl were present in the solution when AgNO 3 was added?

AgNO 3 (aq) + NaCl(aq) → AgCl(s) + NaNO 3 (aq)

Consider the reaction between MnO 2 and HCl:

MnO 2 + 4HCl → MnCl 2 + Cl 2 + 2H 2 O

What is the theoretical yield of MnCl 2 in grams when 165 g of MnO 2 is added to a solution containing 94.2 g of HCl?

Percent Yield

21. In a chemistry experiment, a student obtained 5.68 g of a product. What is the percent yield of the product if the theoretical yield was 7.12 g?

When 38.45 g CCl 4 is reacted with an excess of HF, 21.3 g CCl 2 F 2 is obtained. Calculate the theoretical and percent yields of this reaction.

CCl 4 + 2HF → CCl 2 F 2 + 2HCl

Iron(III) oxide reacts with carbon monoxide according to the equation:

Fe 2 O 3 ( s ) + 3CO( g ) → 2Fe( s ) + 3CO 2 ( g )

What is the percent yield of this reaction if 623 g of iron oxide produces 341 g of iron?

Determine the percent yield of the reaction if 77.0 g of CO 2  are formed from burning 2.00 moles of C 5 H 12  in 4.00 moles of O 2 .

C 5 H 12 + 8 O 2 → 5CO 2  + 6H 2 O

The percent yield for the following reaction was determined to be 84%:

N 2 ( g ) + 2H 2 ( g ) → N 2 H 4 ( l )

How many grams of hydrazine (N 2 H 4 ) can be produced when 38.36 g of nitrogen reacts with 6.68 g of hydrogen?

Silver metal can be prepared by reducing its nitrate, AgNO 3  with copper according to the following equation:

Cu( s ) + 2AgNO 3 ( aq ) → Cu(NO 3 ) 2 ( aq ) + 2Ag( s )

What is the percent yield of the reaction if 71.5 grams of Ag was obtained from 132.5 grams of AgNO 3  ?

Industrially, nitric acid is produced from ammonia by the Ostwald process in a series of reactions:

4NH 3 ( g ) + 5O 2 ( g ) → 4NO( g ) + 6H 2 O( l )

2NO( g ) + O 2 ( g ) → 2NO 2 ( g )

2NO 2 ( g ) + H 2 O( l ) → HNO 3 ( aq ) + HNO 2 ( aq )

Considering that each reaction has an 85% percent yield, how many grams of NH 3 must be used to produce 25.0 kg of HNO 3 by the above procedure?

Aspirin (acetylsalicylic acid) is widely used to treat pain, fever, and inflammation. It is produced from the reaction of salicylic acid with acetic anhydride. The chemical equation for aspirin synthesis is shown below:

In one container, 10.00 kg of salicylic acid is mixed with 10.00 kg of acetic anhydride.

a)  Which reactant is limiting? Which is in excess? b)  What mass of excess reactant is left over? c)  What mass of aspirin is formed assuming 100% yield (Theoretical yield)? d)  What mass of aspirin is formed if the reaction yield is 70.0% ? e)  If the actual yield of aspirin is 11.2 kg, what is the percent yield? f)  How many kg of salicylic acid is needed to produce 20.0 kg of aspirin if the reaction yield is 85.0% ?

3 thoughts on “Stoichiometry Practice Problems”

You forgot the subscript 3 for O in the molecular formula for acetic anhydride and the reaction is not balanced as written. For part F) it’s 18.1 kg and not1.81 kg as written in the final line of the solution.

Thanks for letting me know! Fixed.

You’re welcome!

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5.3.1: Practice Problems Calculating Reaction Yields

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PROBLEM \(\PageIndex{1}\)

The following quantities are placed in a container: 1.5 × 10 24 molecules of diatomic hydrogen, 1.0 mol of sulfur, and 88.0 g of diatomic oxygen.

• What is the total mass in grams for the collection of all three elements?
• What is the total number of moles of atoms for the three elements?
• If the mixture of the three elements formed a compound with molecules that contain two hydrogen atoms, one sulfur atom, and four oxygen atoms, which substance is consumed first?
• How many atoms or molecules of each remaining element would remain unreacted in the change described above ?

4.98 g H 2 , 32 g S; 124.98 g total

2.49 mol H 2 , 2.75 mol O 2 ; 6.24 mol total

S is the limiting reactant (what would be consumed first)

8.978 × 10 23 molecules of H 2 and 4.6 × 10 23 molecules of O 2 remain

PROBLEM \(\PageIndex{2}\)

What is the limiting reactant in a reaction that produces sodium chloride from 8 g of sodium and 8 g of diatomic chlorine?

The limiting reactant is Cl 2

PROBLEM \(\PageIndex{3}\)

Which of the postulates of Dalton's atomic theory explains why we can calculate a theoretical yield for a chemical reaction?

Postulate 4 (A compound consists of atoms of two or more elements combined in a small, whole-number ratio. In a given compound, the numbers of atoms of each of its elements are always present in the same ratio).

PROBLEM \(\PageIndex{4}\)

A student isolated 25 g of a compound following a procedure that would theoretically yield 81 g. What was his percent yield?

\(\mathrm{Percent\: yield = 31\%}\)

PROBLEM \(\PageIndex{5}\)

A sample of 0.53 g of carbon dioxide was obtained by heating 1.31 g of calcium carbonate. What is the percent yield for this reaction?

\[\ce{CaCO3}(s)\rightarrow \ce{CaO}(s)+\ce{CO2}(s)\]

\(\mathrm{Percent\: yield = 91.9\%}\)

PROBLEM \(\PageIndex{6}\)

Freon-12, CCl 2 F 2 , is prepared from CCl 4 by reaction with HF. The other product of this reaction is HCl. Outline the steps needed to determine the percent yield of a reaction that produces 12.5 g of CCl 2 F 2 from 32.9 g of CCl 4 . Freon-12 has been banned and is no longer used as a refrigerant because it catalyzes the decomposition of ozone and has a very long lifetime in the atmosphere. Determine the percent yield.

\(\ce{g\: CCl4\rightarrow mol\: CCl4\rightarrow mol\: CCl2F2 \rightarrow g\: CCl2F2}\)

\(\mathrm{\:percent\: yield=48.3\%}\)

PROBLEM \(\PageIndex{7}\)

Citric acid, C 6 H 8 O 7 , a component of jams, jellies, and fruity soft drinks, is prepared industrially via fermentation of sucrose by the mold Aspergillus niger . The equation representing this reaction is

\[\ce{C12H22O11 + H2O + 3O2 \rightarrow 2C6H8O7 + 4H2O}\]

What mass of citric acid is produced from exactly 1 metric ton (1.000 × 10 3 kg) of sucrose (C 12 H 22 O 11 ) if the yield is 92.30%?

1036 kg citric acid

PROBLEM \(\PageIndex{8}\)

Toluene, C 6 H 5 CH 3 , is oxidized by air under carefully controlled conditions to benzoic acid, C 6 H 5 CO 2 H, which is used to prepare the food preservative sodium benzoate, C 6 H 5 CO 2 Na. What is the percent yield of a reaction that converts 1.000 kg of toluene to 1.21 kg of benzoic acid?

\[\ce{2C6H5CH3 + 3O2 \rightarrow 2C6H5CO2H + 2H2O}\]

\(\mathrm{percent\: yield=91.3\%}\)

PROBLEM \(\PageIndex{9}\)

In a laboratory experiment, the reaction of 3.0 mol of H 2 with 2.0 mol of I 2 produced 1.0 mol of HI. Determine the theoretical yield in grams and the percent yield for this reaction.

512 g (theoretical yield); \(\mathrm{percent\: yield=25\%}\)

PROBLEM \(\PageIndex{10}\)

What is the limiting reactant when 1.50 g of lithium and 1.50 g of nitrogen combine to form lithium nitride, a component of advanced batteries, according to the following unbalanced equation?

\[\ce{Li + N2 \rightarrow Li3N}\]

\[\ce{6Li} + \ce{N2} \rightarrow \: \ce{2Li3N}\]

\[1.50g\: \ce{Li} \times \dfrac{1\: mole\: \ce{Li}}{6.94g\: \ce{Li}} \times\dfrac{2\: mole\: \ce{Li3N}}{6\:mole\: \ce{Li}} = 0.0720\: moles\: \ce{Li3N}\]

\[1.50g\: \ce{N2} \times \dfrac{1\: mole\: \ce{N2}}{28.02g\: \ce{N2}} \times\dfrac{2\: mole\: \ce{Li3N}}{1\:mole\: \ce{N2}} = 0.107\: moles\: \ce{Li3N}\]

\(\ce{Li}\) is the limiting reactant

PROBLEM \(\PageIndex{11}\)

Uranium can be isolated from its ores by dissolving it as UO 2 (NO 3 ) 2 , then separating it as solid UO 2 (C 2 O 4 )·3H 2 O. Addition of 0.4031 g of sodium oxalate, Na 2 C 2 O 4 , to a solution containing 1.481 g of uranyl nitrate, UO 2 (NO 3 ) 2 , yields 1.073 g of solid UO 2 (C 2 O 4 )·3H 2 O.

\[\ce{Na2C2O4 + UO2(NO3)2 + 3H2O ⟶ UO2(C2O4)·3H2O + 2NaNO3}\]

Determine the limiting reactant and the percent yield of this reaction.

Na 2 C 2 O 4 is the limiting reactant. percent yield = 86.6%

PROBLEM \(\PageIndex{12}\)

How many molecules of C 2 H 4 Cl 2 can be prepared from 15 C 2 H 4 molecules and 8 Cl 2 molecules?

Only 8 molecules can be formed

PROBLEM \(\PageIndex{13}\)

How many molecules of the sweetener saccharin can be prepared from 30 C atoms, 25 H atoms, 12 O atoms, 8 S atoms, and 14 N atoms?

Only four molecules can be made.

PROBLEM \(\PageIndex{14}\)

The phosphorus pentoxide used to produce phosphoric acid for cola soft drinks is prepared by burning phosphorus in oxygen.

• What is the limiting reactant when 0.200 mol of P 4 and 0.200 mol of O 2 react according to \[\ce{P4 + 5O2 \rightarrow P4O10}\]
• Calculate the percent yield if 10.0 g of P 4 O 10 is isolated from the reaction.

O 2 is the limiting reactant

\(\mathrm{percent\: yield=88\%}\)

PROBLEM \(\PageIndex{15}\)

Would you agree to buy 1 trillion (1,000,000,000,000) gold atoms for $5? Explain why or why not. Find the current price of gold at http://money.cnn.com/data/commodities/ \(\mathrm{(1\: troy\: ounce=31.1\: g)}\)

This amount cannot be weighted by ordinary balances and is worthless.

Contributors

Paul Flowers (University of North Carolina - Pembroke), Klaus Theopold (University of Delaware) and Richard Langley (Stephen F. Austin State University) with contributing authors.  Textbook content produced by OpenStax College is licensed under a Creative Commons Attribution License 4.0 license. Download for free at http://cnx.org/contents/[email protected] ).

• Adelaide Clark, Oregon Institute of Technology

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Stoichiometry and Percent Yield

In this lesson, we will learn

• Stoichiometry
• Percent Yield
• Limiting Reactants

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